Di-μ-chlorido-bis(chlorido{2-[(4-ethylphenyl)iminomethyl]pyridine-κ2 N,N′}copper(II))
نویسندگان
چکیده
The binuclear title complex, [Cu(2)Cl(4)(C(14)H(14)N(2))(2)], is located on a crystallographic inversion centre. The Cu(II) ion is in a distorted square-pyramid coordination environment formed by the bichelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Cu-Cl bonds is significantly longer than the other.
منابع مشابه
A second monoclinic polymorph of di-μ-chlorido-bis(chlorido{2-[(4-ethylphenyl)iminomethyl]pyridine-κ2 N,N′}copper(II))
The title compound, [Cu₂Cl₄(C₁₄H₁₄N₂)₂], is a new polymorph of a previously reported compound [Dehghanpour et al. (2011 ▶). Acta Cryst. E67, m1296]. The current polymorph was obtained from an acetonitrile solution of the title compound. Like the first polymorph, it is monoclinic (space group P2₁/c). The unique Cu(II) ion in the title centrosymmetric dinuclear complex is in a distorted trigonal-...
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